Synthesis and Crystal Structure of{[Mn(H2O)4(3, 3′-azpy)](3, 3′-azpy)3(PF6)2}n

The complex {[Mn(H2O)4(3, 3?-azpy)](3, 3?-azpy)3(PF6)2}n (3, 3?-azpy = 3, 3?- azobispyridine) has been synthesized and characterized. The crystal (C40H40F12MnN16O4P2, Mr = 1153.76) belongs to the triclinic system, space group P ī with the following crystallographic parameters: a = 10.761(2), b = 11.040(2), c = 23.365(4) ?, ( = 85.52(1), ( = 82.69(1), ( = 70.44(1)°, V = 2592.5(8) ?3, Dc = 1.478 g/cm3, ((MoK() = 4.16 cm-1, F(000) = 1174, Z = 2, final R = 0.0493 and wR = 0.1158 for the observed reflections (I > 2.00((I)). The X-ray analysis revealed that manganese(Ⅱ) cation coordination environment is a distorted octahedral geometry, and the Mn2+ cation is coordinated by four oxygen atoms of water in the equatorial plane, while the two nitrogen atoms of 3, 3?-azpy occupy the axial positions. The complex forms a one-dimensional chain structure via 3, 3?-azpy bridging ligand.

作 者： 李寶龍 曹正白 王壽武 徐正 郁開(kāi)北   作者單位： 李寶龍,曹正白,王壽武(Department of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, China)

徐正(Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China)

郁開(kāi)北(Chengdu Centre of Analysis and Measurement, Academia Sinica, Chengdu 610041, China) 

刊 名： 結(jié)構(gòu)化學(xué)  ISTIC SCI PKU 英文刊名： CHINESE JOURNAL OF STRUCTURAL CHEMISTRY  年，卷(期)： 2002 21(3)  分類號(hào)： O64  關(guān)鍵詞： crystal structure   one-dimensional chain   manganese complex   azobispyridine  

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